Effect of the 44Ca, 29Al, 30Si and 18O isotopic substitution on TO and LO vibrational frequencies of Grossular.
|
IR-TO modes |
IR-LO modes |
||||||||
|
υ |
Δυ |
υ |
Δυ |
||||||
|
|
44Ca |
29Al |
30Si |
18O |
|
44Ca |
29Al |
30Si |
18O |
|
153.4 |
-5.5 |
-0.6 |
0.0 |
-1.3 |
155.2 |
-5.5 |
-0.7 |
0.0 |
-1.5 |
|
183.7 |
-3.2 |
-1.0 |
-0.9 |
-4.5 |
189.0 |
-2.1 |
-1.4 |
-1.3 |
-5.0 |
|
206.9 |
-4.0 |
-0.4 |
-1.6 |
-3.7 |
208.9 |
-5.0 |
-0.2 |
-1.4 |
-3.4 |
|
242.0 |
-3.8 |
-0.8 |
-2.0 |
-5.1 |
248.0 |
-4.1 |
-1.2 |
-2.2 |
-4.4 |
|
303.2 |
-3.3 |
-2.2 |
-0.6 |
-9.5 |
305.8 |
-3.3 |
-2.0 |
-0.7 |
-10.0 |
|
357.5 |
-3.5 |
-5.4 |
-1.5 |
-5.6 |
357.8 |
-3.4 |
-5.6 |
-1.4 |
-5.7 |
|
394.6 |
-1.0 |
-6.4 |
-0.8 |
-12.3 |
406.7 |
-0.3 |
-0.8 |
-0.1 |
-19.2 |
|
407.0 |
-1.4 |
-1.7 |
-0.4 |
-18.4 |
407.9 |
-3.9 |
-6.1 |
-1.1 |
-10.8 |
|
424.2 |
-1.3 |
-6.8 |
-1.8 |
-9.0 |
424.2 |
-0.7 |
-6.6 |
-1.7 |
-8.2 |
|
441.0 |
-3.8 |
-5.7 |
-0.3 |
-8.4 |
480.1 |
-0.3 |
-1.6 |
-0.6 |
-23.1 |
|
480.8 |
-0.1 |
-1.4 |
-0.5 |
-23.7 |
508.6 |
-0.5 |
-2.8 |
-4.0 |
-19.1 |
|
509.3 |
-0.2 |
-1.5 |
-4.0 |
-19.7 |
539.2 |
-2.2 |
-4.6 |
-2.7 |
-15.6 |
|
546.4 |
-0.6 |
-4.0 |
-2.2 |
-19.4 |
583.1 |
-2.2 |
-5.9 |
-1.5 |
-16.0 |
|
625.9 |
-0.3 |
-1.7 |
-4.1 |
-26.6 |
634.4 |
-0.1 |
-1.4 |
-2.4 |
-30.0 |
|
829.6 |
-0.1 |
-0.2 |
-11.9 |
-26.5 |
845.6 |
-0.1 |
-0.3 |
-12.9 |
-25.2 |
|
849.6 |
-0.1 |
-0.3 |
-12.0 |
-27.1 |
879.8 |
-0.3 |
-0.2 |
-10.4 |
-31.0 |
|
901.8 |
-0.3 |
-0.2 |
-12.7 |
-27.8 |
1002.5 |
-0.4 |
-0.9 |
-14.4 |
-30.0 |
Effect of the 44Ca, 59Fe, 30Si and 18O isotopic substitution on TO and LO vibrational frequencies of Andradite.
|
IR-TO modes |
IR-LO modes |
||||||||
|
υ |
Δυ |
υ |
Δυ |
||||||
|
|
44Ca |
59Fe |
30Si |
18O |
|
44Ca |
59Fe |
30Si |
18O |
|
125.4 |
-3.2 |
-1.2 |
-0.1 |
-0.8 |
126.5 |
-3.3 |
-1.3 |
-0.1 |
-0.9 |
|
148.5 |
-1.1 |
-1.6 |
-0.7 |
-3.1 |
149.7 |
-0.8 |
-1.7 |
-0.8 |
-3.1 |
|
184.0 |
-4.9 |
-0.4 |
-0.9 |
-3.0 |
187.6 |
-4.8 |
-0.4 |
-1.0 |
-3.4 |
|
206.3 |
-4.9 |
-0.9 |
-1.0 |
-2.6 |
209.1 |
-5.3 |
-1.1 |
-0.9 |
-2.0 |
|
243.7 |
-2.7 |
-2.7 |
-1.1 |
-3.2 |
244.2 |
-2.6 |
-2.8 |
-1.2 |
-3.2 |
|
271.4 |
-1.9 |
-3.1 |
-0.7 |
-5.9 |
271.5 |
-1.9 |
-3.0 |
-0.7 |
-5.9 |
|
288.0 |
-0.3 |
-4.1 |
-0.9 |
-6.1 |
313.7 |
-1.2 |
-1.5 |
-0.2 |
-12.4 |
|
313.8 |
-1.1 |
-1.6 |
-0.1 |
-12.1 |
323.6 |
-2.4 |
-2.7 |
-1.0 |
-9.2 |
|
340.2 |
-0.9 |
0.0 |
-0.5 |
-17.5 |
345.6 |
-1.3 |
-0.3 |
-1.1 |
-14.6 |
|
366.2 |
-7.8 |
-0.7 |
-0.6 |
-8.6 |
415.6 |
-3.3 |
-1.1 |
-1.8 |
-16.6 |
|
433.2 |
-0.1 |
-0.2 |
-0.4 |
-23.9 |
454.2 |
-2.4 |
-1.7 |
-2.2 |
-13.7 |
|
473.4 |
-0.3 |
-0.4 |
-4.2 |
-19.5 |
482.7 |
-0.6 |
-0.2 |
-3.4 |
-21.2 |
|
503.0 |
-0.4 |
-0.8 |
-4.1 |
-20.4 |
528.1 |
-0.6 |
-0.9 |
-1.4 |
-24.8 |
|
588.4 |
-0.4 |
-0.5 |
-4.1 |
-26.1 |
589.3 |
-0.3 |
-0.5 |
-3.8 |
-26.7 |
|
794.3 |
-0.1 |
-0.1 |
-12.0 |
-24.4 |
807.5 |
0.0 |
-0.1 |
-12.6 |
-23.9 |
|
813.3 |
0.0 |
-0.1 |
-11.6 |
-25.9 |
848.7 |
-0.2 |
0.0 |
-11.0 |
-28.5 |
|
869.6 |
-0.2 |
-0.1 |
-13.1 |
-25.9 |
975.2 |
-0.4 |
-0.2 |
-14.4 |
-29.8 |